METAL COMPLEX-BASED CHEMOSENSORS FOR SELECTIVE SENSING OF BIOLOGICALLY AND ENVIRONMENTALLY SIGNIFICANT IONS
DOI:
https://doi.org/10.29121/shodhkosh.v3.i1.2022.5057Abstract [English]
Chemosensors based on metal complexes are advanced analytical tools designed to detect and quantify specific ions or molecules in various environments. Among the various types, metal complex-based chemosensors have garnered considerable attention due to their high sensitivity, selectivity, and versatility. These chemosensors employ metal complexes as the core sensing units, taking advantage of their unique coordination chemistry and photophysical properties to achieve selective sensing of biologically and environmentally significant ions.
The metal center typically interacts with the analyte, causing a measurable change in the sensor's physical or chemical properties, such as fluorescence, color, or electrical conductivity. This interaction results in high selectivity and sensitivity, making metal complex-based chemosensors ideal for applications in environmental monitoring, biomedical diagnostics, and industrial process control. Their versatility, coupled with the ability to tailor the metal-ligand coordination chemistry, enables precise detection of biologically and environmentally significant ions, contributing to advancements in both scientific research and practical applications.
References
N. Roohani, R. Hurrell, R. Kelishadi, R. Schulin J. Res. Med. Sci., 18 (2013), pp. 144-157
K. Kaur, R. Gupta, S.A. Saraf, S.K. Saraf Compr.Rev. Food. Sci. F, 13 (2014), pp. 358-376 DOI: https://doi.org/10.1111/1541-4337.12067
K.J. Barnham, A.I. Bush Chem. Soc. Rev., 43 (2014), pp. 6727-6749 DOI: https://doi.org/10.1039/C4CS00138A
M.P. Cuajungco, M.S. Ramirez, M.E. Tolmasky Biomedicines, 9 (2021), pp. 208-232 DOI: https://doi.org/10.3390/biomedicines9020208
V.R. Djordjevic, D.R. Wallace, A. Schweitzer, N. Boricic, D. Knezevic, S. Matic, N. Grubor, M. Kerkez, D. Radenkovic, Z. Bulat, B. Antonijevic Environ. Int., 128 (2019), pp. 353-361 DOI: https://doi.org/10.1016/j.envint.2019.04.048
Z. Gao, G.G. Liu, H. Ye, R. Rauschendorfer, D. Tang, X. Xia, Anal. Chem. 89 (2017) 3622–3629. DOI: https://doi.org/10.1021/acs.analchem.6b05026
J. An, R.B. Chen, M.Z. Chen, Y.Q. Hu, Y. Lyu, Y.F. Liu, Sens. Actuators B Chem. 329 (2021), 129097. DOI: https://doi.org/10.1016/j.snb.2020.129097
Z. Xu, X. Chen, H.N. Kim, J. Yoon, Chem. Soc. Rev. 39 (2010) 127–137.
J.J. Lee, Z. Xu, X. Chen, H.N. Kim, J. Yoon, Chem. Soc. Rev. 39 (2010) 127–137. DOI: https://doi.org/10.1039/B907368J
J.J. Lee, S.Y. Lee, K.H. Bok, C. Kim, J. Fluoresc. 25 (2015) 1449–1459. DOI: https://doi.org/10.1007/s10895-015-1635-9
B. L. Vallee and K. H. Falchuk, The biochemical basis of zinc physiology, Physiol. Rev.73 (1993) 79–118. DOI: https://doi.org/10.1152/physrev.1993.73.1.79
D. Martin, M. Rouffet and S. M. Cohen, Illuminating metal ion sensors-benzimidazole sulfonamide metal complexes Inorg. Chem. 49 (2010) 10226–10228
D. Plantone, G.Primiano, R.Renna, D. Restuccia, R. Iorio, K.A. Patanella, M. N. Ferilli, and S. Servidei, Copper deficiency myelopathy: A report of two cases, J Spinal Cord Med. 38(4) (2015) 559–562.
D. Martin, M. Rouffet and S. M. Cohen, Illuminating metal ion sensors-benzimidazole sulfonamide metal complexes Inorg. Chem. 49 (2010) 10226–10228. DOI: https://doi.org/10.1021/ic101700t
D. Plantone, G.Primiano, R.Renna, D. Restuccia, R. Iorio, K.A. Patanella, M. N. Ferilli, and S. Servidei, Copper deficiency myelopathy: A report of two cases, J Spinal Cord Med. 38(4) (2015) 559–562. DOI: https://doi.org/10.1179/2045772314Y.0000000268
L. K. Kirk, Biochemistry of the Halogens and Inorganic Halides, Plenum Press: New York, 1991. DOI: https://doi.org/10.1007/978-1-4684-5817-6
D. Briancon, Fluoride and osteoporosis: an overview, Rev. Rhum. Engl Ed. 64 (1997) 78-8
P.G. Sutariya, N.R. Modi, A. Pandya, B.K. Joshi, K.V. Joshia, S.K. Menon, An ICT based turn on/off quinoline armed calix[4] arene fluoroionophore: its sensing efficiency towards fluoride from waste water and Zn2+ from blood serum, Analyst 137 (2012) 5491–5494. DOI: https://doi.org/10.1039/c2an36247c
C.R. Li, S.L. Li, G.G. Wang, Z.Y. Yang, Spectroscopic properties of a chromone-fluorescein conjugate as Mg2+ “turn on” fluorescent probe, J. Photochem. Photobiol. A: Chem. 356 (2016) 700–707. DOI: https://doi.org/10.1016/j.jphotochem.2016.03.001
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2022 Dr. Meenakshi Ghosh
This work is licensed under a Creative Commons Attribution 4.0 International License.
With the licence CC-BY, authors retain the copyright, allowing anyone to download, reuse, re-print, modify, distribute, and/or copy their contribution. The work must be properly attributed to its author.
It is not necessary to ask for further permission from the author or journal board.
This journal provides immediate open access to its content on the principle that making research freely available to the public supports a greater global exchange of knowledge.
