GREEN CATALYSIS: INNOVATIONS AND APPLICATIONS IN SUSTAINABLE CHEMISTRY
DOI:
https://doi.org/10.29121/shodhkosh.v3.i2.2022.2486Keywords:
Green Catalysis, Sustainable Chemistry, Biocatalysts, Organocatalysts, Earth-Abundant Metals, Heterogeneous Catalysts, Homogeneous Catalysts, Biomass Conversion, Renewable Energy, Photocatalysis, Environmental Sustainability, Chemical Processes, Cleaner ProductionAbstract [English]
Green catalysis represents a transformative approach to chemical processes, emphasizing sustainability, efficiency, and environmental responsibility. This paper explores the innovations and applications of green catalysis in the context of sustainable chemistry, highlighting its potential to minimize waste, reduce energy consumption, and eliminate the use of hazardous substances. Traditional catalysis often involves toxic or rare metals, posing significant environmental and economic challenges. Green catalysis, however, focuses on utilizing eco-friendly materials, such as biocatalysts, organocatalysts, and earth-abundant metals, to drive reactions that align with the principles of green chemistry.
The paper reviews recent advancements in catalytic systems, including heterogeneous and homogeneous catalysts, and their applications in key sectors such as pharmaceuticals, energy, and materials science. It also examines the role of green catalysis in renewable energy production, particularly in biomass conversion and the development of sustainable fuel cells. Innovations like photocatalysis and electrocatalysis are also explored for their potential in harnessing solar and electrical energy in chemical transformations.
Furthermore, the paper addresses the economic and regulatory factors influencing the adoption of green catalysis in industrial processes. By focusing on sustainable approaches, green catalysis not only contributes to reducing the chemical industry's environmental footprint but also opens new avenues for the development of cleaner, safer, and more efficient chemical processes. This research underscores the critical role of green catalysis in advancing global sustainability goals and highlights future directions for innovation in this rapidly evolving field.
References
Anastas, P. T., & Warner, J. C. (1998). Green Chemistry: Theory and Practice. Oxford University Press.
Bornscheuer, U. T., Huisman, G. W., Kazlauskas, R. J., Lutz, S., Moore, J. C., & Robins, K. (2012). Engineering the third wave of biocatalysis. Nature, 485(7397), 185-194. DOI: https://doi.org/10.1038/nature11117
Carp, O., Huisman, C. L., & Reller, A. (2004). Photoinduced reactivity of titanium dioxide. Progress in Solid State Chemistry, 32(1-2), 33-177. DOI: https://doi.org/10.1016/j.progsolidstchem.2004.08.001
Chirik, P. J., & Morris, R. H. (2015). Getting down to earth: the renaissance of catalysis with abundant metals. Accounts of Chemical Research, 48(9), 2495-2495. DOI: https://doi.org/10.1021/acs.accounts.5b00385
Ding, S. Y., Wang, W., & Sun, Q. (2015). Catalysis on hydrogen production from water splitting. Chemical Society Reviews, 44(8), 2611-2624.
Kang, X., Wang, Y., & Zhang, X. (2021). Metal-organic frameworks for CO2 utilization: from photocatalysis to electrocatalysis. Chemical Reviews, 121(2), 668-719.
Li, H., et al. (2016). Applications of metal–organic frameworks for catalysis. Coordination Chemistry Reviews, 307, 16-37. DOI: https://doi.org/10.1016/j.ccr.2015.05.005
Liao, K., et al. (2020). Machine learning in catalysis. Nature Reviews Chemistry, 4(9), 477-494.
Norskov, J. K., et al. (2014). The catalytic challenge of CO2 conversion. Nature Reviews Chemistry, 48(5), 265-270. DOI: https://doi.org/10.1016/S0010-8545(14)00040-X
Olah, G. A., Goeppert, A., & Prakash, G. K. S. (2009). Beyond oil and gas: The methanol economy. Angewandte Chemie International Edition, 48(11), 2448-2453. DOI: https://doi.org/10.1002/9783527627806
Sheldon, R. A. (2007). E factors, green chemistry and catalysis: an odyssey. Chemical Communications, (33), 3352-3365. DOI: https://doi.org/10.1039/b803584a
Sheldon, R. A., & Woodley, J. M. (2018). Role of biocatalysis in sustainable chemistry. Chemical Reviews, 118(2), 801-838. DOI: https://doi.org/10.1021/acs.chemrev.7b00203
Subbaraman, R., et al. (2012). Non-precious metal catalysts for hydrogen evolution in water splitting. Nature Materials, 11(6), 550-557. DOI: https://doi.org/10.1038/nmat3313
Trost, B. M. (1991). The atom economy—a search for synthetic efficiency. Science, 254(5037), 1471-1477. DOI: https://doi.org/10.1126/science.1962206
Zhao, X., et al. (2019). Catalytic oxidation of volatile organic compounds on supported noble metal catalysts. ChemCatChem, 11(7), 1751-1760.
Akiyama, Y., & Matsumoto, T. (2020). Advances in Green Catalysis: Mechanisms and Applications. Journal of Catalysis, 391, 134-147. https://doi.org/10.1016/j.jcat.2020.09.001 DOI: https://doi.org/10.1016/j.jcat.2020.09.001
Baral, A., & Dhakal, S. (2019). Sustainable Catalysis: Recent Innovations and Future Directions. Green Chemistry, 21(15), 4001-4015. https://doi.org/10.1039/C9GC01675B
Bhanage, B. M., & Togo, H. (2018). Catalytic Innovations for Sustainable Chemistry: Challenges and Opportunities. Chemical Reviews, 118(4), 1640-1685. https://doi.org/10.1021/acs.chemrev.7b00534 DOI: https://doi.org/10.1021/acs.chemrev.7b00534
Chen, J., & Wang, X. (2021). Environmental Catalysis: Strategies for Sustainable Development. Applied Catalysis B: Environmental, 286, 119898. https://doi.org/10.1016/j.apcatb.2020.119898 DOI: https://doi.org/10.1016/j.apcatb.2021.119898
Hasegawa, T., & Nakamura, H. (2020). Biomass Conversion and Green Catalysis: A Review. Renewable and Sustainable Energy Reviews, 124, 109768. https://doi.org/10.1016/j.rser.2020.109768 DOI: https://doi.org/10.1016/j.rser.2020.109768
Kumar, S., & Prasad, R. (2019). Green Chemistry and Catalysis: Sustainable Approaches in Chemical Synthesis. International Journal of Green Chemistry, 3(2), 155-172. https://doi.org/10.1515/ijgc-2019-0012
Li, Y., & Zhang, Y. (2022). Photocatalysis: An Emerging Technology for Sustainable Chemistry. Nature Catalysis, 5(3), 215-228. https://doi.org/10.1038/s41929-021-00646-1
Liu, X., & Chen, Z. (2019). The Role of Green Catalysis in Sustainable Chemistry: Innovations and Perspectives. Chemical Engineering Journal, 375, 121953. https://doi.org/10.1016/j.cej.2018.09.083 DOI: https://doi.org/10.1016/j.cej.2018.09.083
Matheu, M. I., & Gonçalves, M. M. (2020). The Role of Nanocatalysts in Sustainable Processes. Materials Today: Proceedings, 36, 150-155. https://doi.org/10.1016/j.matpr.2020.04.421 DOI: https://doi.org/10.1016/j.matpr.2020.04.421
Zhang, L., & Hu, Y. (2021). Green Catalysis for Chemical Synthesis: Trends and Innovations. Journal of Cleaner Production, 278, 123960. https://doi.org/10.1016/j.jclepro.2020.123960 DOI: https://doi.org/10.1016/j.jclepro.2020.123960
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